Monday, 8 February 2016

Aldehydes are typically more reactive than ketones

Aldehydes are more reactive than ketones in nucleophilic addition react

        Sterics
 
  • Aldehydes are sterically less hindered than ketones (as hydrogen atom is smaller than any other organic group).
 
 

 Charge

  • The carbonyl carbon in aldehydes generally has more partial positive charge than in ketones due to the electron-donating nature of alkyl groups. 
          Aldehydes only have one e- donor group while ketones have two.

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